Chiral Ruthenium(II) Complexes as Supramolecular Building Blocks for Heterometallic Self-Assembly
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https://figshare.com/articles/dataset/Chiral_Ruthenium_II_Complexes_as_Supramolecular_Building_Blocks_for_Heterometallic_Self-Assembly/4270196
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资源简介：
A series
of enantiopure ruthenium(II) polypyridyl complexes are reported that
feature pendant pyridyl groups suitable for building larger self-assembled
structures. The complexes are characterized in detail in solution
using NMR spectroscopy, cyclic voltammetry, and photophysical methods
and in the solid state using single-crystal X-ray crystallography.
The complexes are luminescent, displaying long excited-state lifetimes
that are quenched when the pendant pyridyl groups are protonated.
Reaction with cadmium(II) ions results in the formation of a mixed-metal
one-dimensional coordination polymer, which was characterized by single-crystal
X-ray crystallography.
创建时间：
2016-11-30
