Oxidative Addition of σ Bonds to an Al(I) Center
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https://figshare.com/articles/dataset/Oxidative_Addition_of_Bonds_to_an_Al_I_Center/2280009
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资源简介：
The
Al(I) compound NacNacAl (1, NacNac = [ArNC(Me)CHC(Me)NAr]− and Ar = 2,6-Pri2C6H3) reacts with H–X (X = H, Si, B, Al, C, N, P,
O) σ bonds of H2, silanes, borane (HBpin, pin = pinacolate),
allane (NacNacAlH2), phosphine (HPPh2), amines,
alcohol (PriOH), and Cp*H (Cp* = pentamethylcyclopentadiene)
to give a series of hydride derivatives of the four-coordinate aluminum
NacNacAlH(X), which are characterized herein by spectroscopic methods
(NMR and IR) and X-ray diffraction. This method allows for the syntheses
of the first boryl hydride of aluminum and novel silyl hydride and
phosphido hydride derivatives. In the case of the addition of NacNacAlH2, the reaction is reversible, proving the possibility of reductive
elimination from the species NacNacAlH(X).
创建时间：
2016-02-17
