A Rare Example of Efficient Alkene Hydrogenation Mediated by a Neutral Iridium(I) Complex under Mild Conditions
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https://figshare.com/articles/dataset/A_Rare_Example_of_Efficient_Alkene_Hydrogenation_Mediated_by_a_Neutral_Iridium_I_Complex_under_Mild_Conditions/3246235
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资源简介：
The synthesis and characterization of two new
square-planar (COD)M(κ2-P,O-phosphinoenolate) complexes
(M = Rh, 3a; M = Ir, 3b; COD = η4-1,5-cyclooctadiene) are
described. Complex 3b represents an unusual example of a
neutral (not cationic) square-planar Ir(I) complex that is capable
of mediating the reduction of alkenes under mild benchtop
conditions (∼1 atm of H2, 22 °C) in the presence of high-polarity
(THF, CH2Cl2, CH3CN) and low-polarity solvents (hexanes,
benzene).
创建时间：
2016-05-05
