Regulation of Iron-Catalyzed Olefin Hydroboration by Ligand Modifications at a Remote Site
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https://figshare.com/articles/dataset/Regulation_of_Iron_Catalyzed_Olefin_Hydroboration_by_Ligand_Modifications_at_a_Remote_Site/2219653
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资源简介：
An
amide-derived N,N,N-Fe(II) complex catalyzes the hydroboration of alkenes
at room temperature. Alkylation of a remote site on the ligand backbone
was used as a late-stage modification to provide a more electrophilic
complex as determined by electrochemical studies. The alkylated variant,
compared to the parent complex, catalyzes olefin hydroboration with
an increased reaction rate and exhibits distinct regioselectivity
for internal alkene hydroboration.
创建时间：
2015-01-02
