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Unprecedented Nitronyl Nitroxide Bridged 3d–4f Complexes: Structure and Magnetic Properties

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NIAID Data Ecosystem2026-03-07 收录
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https://figshare.com/articles/dataset/Unprecedented_Nitronyl_Nitroxide_Bridged_3d_4f_Complexes_Structure_and_Magnetic_Properties/2360692
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Two novel 2p–3d–4f compounds, {Ln­(hfac)3[Cu­(hfac)2]3(NITPhPyrim)2} [Ln = Gd (1), Dy (2)], have been obtained by reacting phenyl pyrimidyl nitronyl nitroxide with Cu­(hfac)2 and Ln­(hfac)3. These two compounds are the first examples of two-dimensional 3d–4f complexes bridged by nitronyl nitroxide radicals. Overall ferromagnetic behaviors were observed in both compounds.
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2016-02-18
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