Reactions of [Ru(CO)<sub>2</sub>(PPh<sub>3</sub>)<sub>3</sub>] with Alkynylphosphonium Salts: Phosphaallenylidene vs Phosphonioacetylide Coordination
收藏NIAID Data Ecosystem2026-03-06 收录
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资源简介：
[Ru(CO)2(PPh3)3] reacts with [Me3SiCCPPh3]OTf in the presence of moist [nBu4N]F to provide the C−H activation product [RuH(CCPPh3)(CO)2(PPh3)2]OTf, spectroscopic and structural data for which are used to assess the previously proposed analogy between phosphonioacetylide and phosphaallenylidene (cf. isonitriles) bonding descriptions in an organometallic context.
创建时间：
2016-02-26
