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Pyridine-NHC: Effective Ligand in Pd-Catalyzed Cyclopropanation of Esters with Substituted Allyl Carbonates

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NIAID Data Ecosystem2026-03-09 收录
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https://figshare.com/articles/dataset/Pyridine_NHC_Effective_Ligand_in_Pd_Catalyzed_Cyclopropanation_of_Esters_with_Substituted_Allyl_Carbonates/2223691
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By consideration of the mechanism of Pd-catalyzed cyclopropanation and allylation, NHC-pyridine compounds were adopted as the ligand in Pd-catalyzed cyclopropanation of esters and monosubstituted allylic reagents. The corresponding cyclopropanes were afforded as major products in moderate to good yields with high cyclopropane/allylation selectivity.
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2016-02-16
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