Metallo-Cryptophanes Decorated with Bis-N-Heterocyclic Carbene Ligands: Self-Assembly and Guest Uptake into a Nonporous Crystalline Lattice
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https://figshare.com/articles/dataset/Metallo_Cryptophanes_Decorated_with_Bis_N_Heterocyclic_Carbene_Ligands_Self_Assembly_and_Guest_Uptake_into_a_Nonporous_Crystalline_Lattice/2041890
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资源简介：
Pd3L2 metallo-cryptophane cages with cyclotriveratrylene-type
L ligands can be stabilized by use of a bis-N-heterocyclic carbene
as an auxiliary cis-protecting ligand, while use
of more common protecting chelating ligands such as ethylenediamine
saw a Pd3L2 to Pd6L8 rearrangement
occur in solution. The crystalline Pd3L2 complexes
act as sponges, taking up 1,2-dichorobenzene or iodine in a single-crystal-to-single-crystal
fashion despite not exhibiting conventional porosity.
创建时间：
2015-12-17
