Cs8UIV(UVIO2)3(Ge3O9)3·3H2O: A Mixed-Valence Uranium Germanate with 9-Ring Channels
收藏Figshare2016-02-23 更新2026-04-29 收录
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https://figshare.com/articles/dataset/Cs_sub_8_sub_U_sup_IV_sup_U_sup_VI_sup_O_sub_2_sub_sub_3_sub_Ge_sub_3_sub_O_sub_9_sub_sub_3_sub_3H_sub_2_sub_O_A_Mixed_Valence_Uranium_Germanate_with_9_Ring_Channels/2652712
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A mixed-valence uranium(IV,VI) germanate has been synthesized under high-temperature, high-pressure hydrothermal conditions. The structure contains discrete UIVO6 octahedra and UVIO6 tetragonal bipyramids, which are connected by three-membered single-ring Ge3O96– anions to form a three-dimensional framework with 9-ring channels. The U 4f X-ray photoelectron spectroscopy spectrum was measured to identify the valence states of the uranium.
创建时间：
2016-02-23
