A New Route to Ruthenium Thiolate Alkylidene Complexes
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资源简介：
(Im(OMe)2)(SIMes)(PPh3)RuHCl (Im(OMe)2 = (C3H2(NCH2CH2OMe)2) reacts with aryl vinyl sulfides (PhSCHCH2 and (C6F5)SCHCHPh) to give the Ru thiolate alkylidene complexes (Im(OMe)2)(SIMes)(PhS)RuCl(CHCH3) and (Im(OMe)2)(SIMes)(F5C6S)RuCl(CHCH2Ph), which are shown to be effective olefin metathesis catalysts upon activation with BCl3.
创建时间：
2016-02-18
