Molecular Thioamide ↔ Iminothiolate Switches for Sulfur Mustards
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https://figshare.com/articles/dataset/Molecular_Thioamide_Iminothiolate_Switches_for_Sulfur_Mustards/2560516
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资源简介：
SNS platinum(II) pincer complexes reversibly bind and
release the
surrogate half sulfur mustard, 2-chloroethyl ethyl sulfide (CEES).
The switch-like behavior of the pincers is attributed to a reversible
transformation between the thioamide and iminothiolate forms of the
pincer skeleton under slightly acidic and basic conditions, respectively.
An amide-based palladium(II) pincer complex also binds CEES, as confirmed
crystallographically and by NMR.
创建时间：
2016-02-22
