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A [2 + 3] Reductive Cyclodimerization of Quinoline by SmI2

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Figshare2016-02-13 更新2026-04-29 收录
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https://figshare.com/articles/dataset/A_2_3_Reductive_Cyclodimerization_of_Quinoline_by_SmI_sub_2_sub_/2134756
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Pyridine and its derivatives are rather difficult to reduce, and the products often undergo a very fast reoxidation to regain aromaticity. The reduction of quinoline by SmI2 results in an instantaneous [2 + 3] cyclization reaction, forming a bridged seven-membered ring within a polycyclic system.
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2016-02-13
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