Enantiospecific Generation and Trapping Reactions of Aryne Atropisomers
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https://figshare.com/articles/dataset/Enantiospecific_Generation_and_Trapping_Reactions_of_Aryne_Atropisomers/13014191
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资源简介：
Enantioenriched aryne
atropisomers having a biaryl stereogenic
axis vicinal to the reactive triple bond are demonstrated to exist.
These reaction intermediates are easily produced in situ and can undergo
the standard aryne cycloaddition chemistry in an enantiospecific manner.
Notably, the aryne atropisomers herein have allowed the practical
syntheses of a small nanographene as well as some triptycene and anthracene
derivatives that embed stereogenic axes of controlled absolute configurations.
创建时间：
2020-09-21
