First Asymmetric Total Syntheses of Fawcettimine-Type <i>Lycopodium</i> Alkaloids, Lycoposerramine-C and Phlegmariurine-A
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A successful asymmetric total synthesis of lycoposerramine-C involving such key steps as a cobalt-mediated Pauson−Khand reaction and vinyl Claisen rearrangement and its biomimetic transformation to phlegmariurine-A are described.
创建时间:
2009-12-03



