An Oxide Ion Encapsulating Tetraholmium Tetrahedron Stabilized by Complexation with the “Carbons Apart” C<sub>2</sub>B<sub>4</sub>-Carborane Ligands
收藏NIAID Data Ecosystem2026-03-06 收录
数据链接：
官方服务：
资源简介：
The reaction of closo-exo-5,6-Na(THF)2-1-Na(THF)2-2,4-(SiMe3)2-2,4-C2B4H4 with HoCl3 and H2O in a molar ratio of 5:4:1 produces the new holmacarborane cluster {[η5-1-Ho(THF)-2,3-(SiMe3)2-2,3-C2B4H4]4(μ-Cl)2(μ4-O)} as a pale yellow crystalline solid in 86% yield. The crystal structure shows that the core of the cluster consists of four Ho atoms that tetrahedrally surround an oxygen atom.
创建时间：
2003-10-27
