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Concise Synthesis of Phospholene and Its P‑Stereogenic Derivatives

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Figshare2020-05-07 更新2026-04-28 收录
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https://figshare.com/articles/dataset/Concise_Synthesis_of_Phospholene_and_Its_P_Stereogenic_Derivatives/12330911
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A simple method to build phospholene derivatives has been achieved in a one-pot reaction with readily available o-alkynylaryl bromides and alkylphosphine oxides. This method is also applicable to synthesize P-stereogenic phospholenes, and the resulting chiral phosphine was utilized as a ligand for coordination chemistry.
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2020-05-07
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