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Cocrystal and Salts of 2,2′,6,6′-Tetracarboxybiphenyl with Bis(pyridyl) Derivatives: Eight-fold Interpenetrated Diamondoid and Layered Networks

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The cocrystallization reactions of 2,2′,6,6′-tetracarboxybiphenyl with bis(4-pyridyl) ethylene and 4,4′-bipyridine were studied, and it was found that molecular symmetry (pseudo-S4) has been transferred into supramolecular symmetry to form an 8-fold interpenetrated diamondoid network only in the case of cocrystals but not in the case of salts.

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2016-02-25
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