Eclipsed M<sub>2</sub>X<sub>6</sub> Compounds Exhibiting Very Short Metal−Metal Triple Bonds
收藏NIAID Data Ecosystem2026-03-06 收录
数据链接：
官方服务：
资源简介：
The preparation, characterization, and electronic structure of homoleptic complexes of molybdenum and tungsten bridged by bis(alkylamido)phenylboranes, M2[RN−BPh−NR]3 (M = Mo, R = Et (1), iPr (2); M = W, R = Et (3), iPr (4)), are described. These triple metal−metal bond species (i) exhibit a nearly eclipsed ligand geometry and (ii) possess the shortest metal−metal bonds of neutral dimolybdenum and ditungsten M2X6 complexes observed to date (d(Mo−Mo) = 2.1612(6) Å (1); d(W−W) = 2.2351(7) Å (4)).
创建时间：
2016-05-07
