Ruthenium-Catalyzed Heck-Type Alkenylation of Alkyl Bromides
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https://figshare.com/articles/dataset/Ruthenium-Catalyzed_Heck-Type_Alkenylation_of_Alkyl_Bromides/8248481
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资源简介：
The complex [Cp*RuCl(PPh3)2] displays a high
catalytic activity for the Heck-type alkenylation of alkyl bromides
in the first example using this metal under thermal conditions. The
coupling reaction proceeds efficiently with a variety of functionalized
tertiary, secondary, and primary alkyl bromides. The presence of Hünig’s
base has been revealed to be crucial for this transformation. Preliminary
mechanistic studies support the participation of alkyl radicals in
the reaction.
创建时间：
2019-05-27
