Progress toward the Total Synthesis of (+)-Aldosterone: Synthesis of the A−D Rings
收藏NIAID Data Ecosystem2026-03-06 收录
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Synthesis of the A−D rings of the cortical hormone (+)-aldosterone is described. The key step incorporates a chiral tether in a type 2 intramolecular Diels−Alder reaction that establishes the absolute configuration of four contiguous asymmetric centers. This approach provides an efficient route for either enantiomer of the steroid skeleton.
创建时间：
2016-08-20
