C–H Activation/Functionalization Catalyzed by Simple, Well-Defined Low-Valent Cobalt Complexes
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https://figshare.com/articles/dataset/C_H_Activation_Functionalization_Catalyzed_by_Simple_Well_Defined_Low_Valent_Cobalt_Complexes/2192833
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资源简介：
A facile
C–H activation and functionalization of aromatic
imines is presented using low-valent cobalt catalysts. Using Co(PMe3)4 as catalyst we have developed an efficient and
simple protocol for the C–H/hydroarylation of alkynes with
an anti selectivity. Deuterium-labeling experiments,
DFT calculations coupled with the use of a well-defined catalyst have
for the first time shed light on the elusive black box of cobalt catalyzed
C–H functionalization.
创建时间：
2016-02-14
