Ru Complex Based on the Rigid Trans-1,2-bis(diphenylphosphino)ethylene Ligand: An Efficient In Situ-Formed Bimetallic Homogeneous Catalyst for Formic Acid Dehydrogenation

This dataset comprises the primary experimental data supporting the synthesis and catalytic application of a novel in situ-formed bimetallic complex. The provided files include crystallographic data (SC-XRD) utilized for structural confirmation, alongside comprehensive spectroscopic (NMR, FT-IR) and chromatographic (GC) data. These datasets form the empirical basis for the performance metrics and kinetic/mechanistic investigations presented in the associated manuscript.