Dinitrogen Reduction by a Chromium(0) Complex Supported by a 16-Membered Phosphorus Macrocycle
收藏NIAID Data Ecosystem2026-03-07 收录
下载链接：
https://figshare.com/articles/dataset/Dinitrogen_Reduction_by_a_Chromium_0_Complex_Supported_by_a_16_Membered_Phosphorus_Macrocycle/2389801
下载链接
链接失效反馈官方服务：
资源简介：
We
report a rare example of a Cr–N2 complex supported
by a 16-membered phosphorus macrocycle containing pendant amine bases.
Reactivity with acid afforded hydrazinium and ammonium, representing
the first example of N2 reduction by a Cr–N2 complex. Computational analysis examined the thermodynamically
favored protonation steps of N2 reduction with Cr leading
to the formation of hydrazine.
创建时间：
2013-08-07
