Solvothermal Syntheses, Crystal Structures, and Thermal Properties of New Manganese Thioantimonates(III): The First Example of the Thermal Transformation of an Amine-Rich Thioantimonate into an Amine-Poorer Thioantimonate

Two new neutral thioantimonates(III) were first prepared by the reaction of elemental manganese, antimony, and
sulfur in tren (tren = tris(2-aminoethyl)amine, C6H18N4) at 140 °C. In the amine-rich compound [Mn(tren)]2Sb2S5
(1) the trigonal SbS3 pyramids are connected via common corners (S(3)) into the tetradentate [Sb2S5]4- anion.
Four S atoms have bonds to the manganese atoms of the [Mn(tren)2+] cations. A special structural feature is the
large Sb−S(3)−Sb(a) angle of 134°. Density functional calculations clearly demonstrate that this large angle results
from the steric interactions between the two Mn(tren) subunits. In the crystal structure of the amine-poorer compound
[Mn(tren)]2Mn2Sb4S10 (2), MnS4 tetrahedra and SbS3 pyramids are linked via common corners and edges to form
a new heterometallic [Mn2Sb4S10] core. The [Mn(C6H18N4)2+] cations are located at the periphery of the core and
are bound to the [Mn2Sb4S10] unit via two S atoms. The thermal behavior of both compounds was investigated
using simultaneous thermogravimetry (TG), differential thermoanalysis, and mass spectroscopy. The amine-richer
compound 1 decomposes in three steps upon heating. After the first TG step an intermediate phase is formed,
which was identified as the amine-poorer compound 2 by X-ray diffraction. Reaction of compound 2 at 140 °C with
an excess of tren forms the amine-rich compound 1.