Zero/one-dimensional coordination complexes constructed from the carboxylate and multi-nitrogen chelating ligands: structural insights and photocatalytic degradation of organic dye
收藏资源简介：
In the current study, two new coordination complexes with the chemical formulae of [Co(cbba)(bimb)](H<sub>2</sub>O) (<b>1</b>, H<sub>2</sub>cbba = 3-((3-carboxybenzyl)oxy)benzoic acid, bimb = 6,6′-bis(1H-benzo[d]imidazol-2-yl)-2,2’-bipyridine) and {[Co(pdc)(bimb)](DMF)}<sub>n</sub> (<b>2</b>, H<sub>2</sub>pda = pyrazine-2,5-dicarboxylic acid) have been successfully prepared by reaction of the Co(NO<sub>3</sub>)<sub>2</sub>·6H<sub>2</sub>O with the bimb ligand in the presence of different carboxylate ligands (H<sub>2</sub>cbba for <b>1</b> and H<sub>2</sub>pda for <b>2</b>). The as-prepared two complexes have been determined via the elemental analysis, single crystal X-ray diffraction along with the powder X-ray diffraction. In addition, the photocatalytic activity of complex <b>2</b> toward the degradation of methyl violet (MV) in simulated polluted water was explored.
