Homolytic Cleavage Reactions of a Neutral Doubly Base Stabilized Diborane(4)
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https://figshare.com/articles/dataset/Homolytic_Cleavage_Reactions_of_a_Neutral_Doubly_Base_Stabilized_Diborane_4_/5289994
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资源简介：
The neutral doubly base stabilized
diborane(4) [C2H2(NCH2C6H4)2CB]2 (3a), featuring
an electron-precise B(sp3)–B(sp3) σ
bond, was generated by
one-electron reduction of the corresponding borenium precursor with
Cp*2Co followed by dimerization. Compound 3a reacts with TEMPO, (PhC(O)O)2, PhNO, (tht)AuCl (tht =
tetrahydrothiophene), and S8. The resulting species, (C2H2(NCH2C6H4)2CB)(L) (L = ONC5H6Me4 (4), OC(O)Ph (5), PhNO (6), Cl (7)) and [(C2H2(NCH2C6H4)2CB)2(S4)]
(8), have been fully characterized and are consistent
with homolytic cleavage of the B–B bond in 3a.
创建时间：
2017-08-09
