Stability and Porosity Enhancement through Concurrent Ligand Extension and Secondary Building Unit Stabilization
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https://figshare.com/articles/dataset/Stability_and_Porosity_Enhancement_through_Concurrent_Ligand_Extension_and_Secondary_Building_Unit_Stabilization/3058873
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资源简介：
A trigonal nanosized carboxylate ligand, 1,3,5-tris[4‘-carboxy(1,1‘-biphenyl-4-yl)]benzene (TCBPB), has been synthesized and applied
in the construction of porous metal−organic frameworks (MOFs).
A solvothermal reaction of TCBPB and a zinc salt in the presence
of pyridine produces 1, an unstable MOF consisting of a tetrazinc
secondary building unit (SBU) with labile terminal ligands. Changing
pyridine to a noncoordinating base in the assembly procedure
affords 2, a stable MOF with permanent porosity containing an
octazinc SBU without labile terminal ligands.
创建时间：
2006-09-18
