Instant “Base-Promoted” Generation of Roper's-type Ru(0) Complexes Ru(CO)<sub>2</sub>(PR<sub>3</sub>)<sub>3</sub> from a Simple Carbonylchlororuthenium(II) Precursor
收藏NIAID Data Ecosystem2026-03-06 收录
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An uncommon synergism in the concerted action of OH- and PR3 toward the simple Ru(II) complex Ru(CO)3Cl2(thf) allows a highly efficient reduction of the metal in ethanol or acetonitrile solution at 0 °C, with selective production of the corresponding Roper's-type Ru(0) complexes Ru(CO)2(PR3)3 in high yields within 10 min.
创建时间：
2016-05-05
