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Comparison of 2‑Arylnaphtho[2,3‑b]phospholes and 2‑Arylbenzo[b]phospholes: Effects of 2‑Aryl Groups and Fused Arene Moieties on Their Optical and Photophysical Properties

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Figshare2016-02-13 更新2026-04-29 收录
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Suzuki–Miyaura cross-coupling reactions were used in the divergent synthesis of a series of 2-arylnaphtho­[2,3-b]­phosphole P-oxides and their benzo­[b]­phosphole counterparts. We elucidated the electronic and steric effects of the 2-aryl groups and fused arene moieties on the optical and photophysical properties of these two types of phosphole-based π-systems.

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2016-02-13
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