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BaFe9LiO15: A New Layered Antiferromagnetic Ferrite

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Figshare2016-02-19 更新2026-04-29 收录
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https://figshare.com/articles/dataset/BaFe_sub_9_sub_LiO_sub_15_sub_A_New_Layered_Antiferromagnetic_Ferrite/2417926
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The new Fe3+ oxide BaFe9LiO15 is isostructural with the magnetically frustrated material BaV10O15, adopting a structure based on the stacking of close-packed pure oxide and BaO7 layers. Neutron diffraction and Mössbauer spectroscopy shows that BaFe9LiO15 is long-range antiferromagnetically ordered with a Néel temperature of 460 K. The magnetic ordering of antiferromagnetically coupled ferromagnetic planes is stabilized by 90° and 180° superexchange interactions between the Fe3+ cations that supersede the frustrated in-plane direct exchange observed in t2g-only systems.
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2016-02-19
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