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Regioselective Synthesis of Phenoxathiin Derivatives under Transition-Metal-Free Conditions

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DataCite Commons2020-08-02 更新2024-07-13 收录
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A simple and efficient method was developed for the synthesis of phenoxathiin derivatives. A range of 1,2-dihaloarenes or 1-halo-2-nitroarenes reacted with 2-sulfanylphenol to give the desired products in good-to-excellent yields. It is intriguing that 1-halo-2-nitroarenes containing electron-donating groups worked well as substrates in this reaction.

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2013-03-01
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