five

Bile Acid-Based Cage Compounds with Lipophilic Outer Shells and Inner Cavities

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https://figshare.com/articles/dataset/Bile_Acid_Based_Cage_Compounds_with_Lipophilic_Outer_Shells_and_Inner_Cavities/2641099
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资源简介:
The uniquely functionalized steroid-based cyclodimers 4, cis-5, and trans-5 have been synthesized and fully characterized.The cyclodimer 5, with a cis–trans ratio of 3:1, is obtained by coupling the terminal alkenes of two 4-pentenoate groups on a cyclodimer 4 via Grubbs’ intramolecular ring-closing metathesis. The crystal structure shows cis-5 to be a cagelike cyclic oligomer bridged by the flexible oct-4-enedioate link.
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2011-06-17
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