Organocatalytic Asymmetric Anti-Selective Michael Reactions of Aldehydes and the Sequential Reduction/Lactonization/Pauson–Khand Reaction for the Enantioselective Synthesis of Highly Functionalized Hydropentalenes
收藏Figshare2016-02-20 更新2026-04-29 收录
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https://figshare.com/articles/dataset/Organocatalytic_Asymmetric_i_Anti_i_Selective_Michael_Reactions_of_Aldehydes_and_the_Sequential_Reduction_Lactonization_Pauson_Khand_Reaction_for_the_Enantioselective_Synthesis_of_Highly_Functionalized_Hydropentalenes/2476879
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资源简介：
A new method has been developed for the enantioselective synthesis of highly functionalized hydropentalenes bearing up to four stereogenic centers with high stereoselectivity (up to 99% ee). This process combines an enantioselective organocatalytic anti-selective Michael addition with a highly efficient one-pot reduction/lactonization/Pauson–Khand reaction sequence. The structures and absolute configurations of the products were confirmed by X-ray analysis.
创建时间：
2016-02-20
