Bicyclic Phosphite Esters from Pentaerythritol and Dipentaerythritol: New Bridging Ligands in Organometallic and Inorganic Chemistry
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https://figshare.com/articles/dataset/Bicyclic_Phosphite_Esters_from_Pentaerythritol_and_Dipentaerythritol_New_Bridging_Ligands_in_Organometallic_and_Inorganic_Chemistry/3341824
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资源简介：
Transesterification reactions yield bicyclic (caged) phosphite esters P(OCH2)3CCH2OH (1)
and (P(OCH2)3CCH2)2O (2), and P(OCH2)3CCH2O2CR (R = Ph, 3; 4-tBuC6H4, 4; 4-O2NC6H4,
5; 3-pyridyl, 6; 4-pyridyl, 7; 1/2 p-C6H4, 8; 1/2 m-C6H4, 9; 1/3 1,3,5-C6H3, 10), which can act as
ligands. Metal-bridged complexes and X-ray structures of 7, {[(η5-MeCp)Mn(CO)2]2(μ-2)} (11),
and [CuBr(2)]∞·MeCN (12) are reported.
创建时间：
2016-05-07
