Rearrangement in a Tripodal Nitroxide Ligand To Modulate the Reactivity of a Ti–F Bond
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https://figshare.com/articles/dataset/Rearrangement_in_a_Tripodal_Nitroxide_Ligand_To_Modulate_the_Reactivity_of_a_Ti_F_Bond/2125711
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资源简介：
The tripodal nitroxide ligand [(2-tBuNO)C6H4CH2)3N]3– (TriNOx3–)
binds the Ti(IV) cation and prevents inner-sphere coordination of
chloride in the complex [Ti(TriNOx)]Cl (1). The ligand
undergoes an η2-NO to κ1-O rearrangement
to enable a fluoride ion to bind in the related complex Ti(TriNOx)F
(2). Computational and reactivity studies demonstrated
that the ligand rearrangement contributed to the enthalpy change in
the transfer of a fluoride anion.
创建时间：
2016-02-12
