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Balancing the heat requirements of an endothermic reaction with heat generated by an exothermic reaction

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DataONE2023-05-10 更新2024-06-08 收录
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Reactor designs suffer from a fundamental limitation resulting from the flow configuration in which a reacting stream flows parallel to a heat transfer surface through which the majority of heat is transferred perpendicular to the direction of fluid flow. Regardless of the reaction taking place in the reaction channels, its reaction rate will vary along the flow length of that channel due to changes in concentration and temperature. Balancing the heat requirements of an endothermic reaction with heat generated by an exothermic reaction flowing parallel to and on the opposite side of a separating plate is extraordinarily difficult since the endothermic reaction is likely to have a very different dependence upon concentration and temperature than the endothermic reaction. Along the flow length of the plate that divides these reactions, the heat flux through the plate that is perpendicular to fluid flow will vary due to temperature and reaction rate differences along the flow length of the plate. Since the thermally coupled reactions are so closely coupled, neither reaction can run at a significantly different reaction rate at any point along the channel length. Thus, each reaction will exhibit a peak in reaction rate at nearly the same position within the reactor with slower reaction rates before and after this peak, which leads to the need for a long reactor channel to ensure complete conversion.
创建时间:
2023-11-08
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