A Terthiophene-Containing Alkynylplatinum Terpyridine Pacman Complex: Controllable Folding/Unfolding Modulated by Weak Intermolecular Interactions
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https://figshare.com/articles/dataset/A_Terthiophene_Containing_Alkynylplatinum_Terpyridine_Pacman_Complex_Controllable_Folding_Unfolding_Modulated_by_Weak_Intermolecular_Interactions/2413459
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Folded and unfolded solid-state structures of a bimetallic alkynylplatinum terpyridine complex with a flexible terthiophene linker have been obtained. Weak intermolecular interactions including π–π stacking and C–H···O and C–H···Cl interactions as well as Cl−π interactions stabilize the folded structure. In solution, folding is studied by electronic absorption spectroscopy and 1H and NOESY NMR experiments.
创建时间:
2016-02-19



