Total Synthesis of 20-Norsalvinorin A. 1. Preparation of a Key Intermediate
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The key tricylic intermediate 3a, for the total synthesis of the C20-nor analogue of salvinorin A, was prepared in seven steps from 3-furaldehyde. Key steps involved a highly regio- and diastereoselective Lewis acid assisted Diels−Alder reaction followed by base-promoted epimerization and a completely stereoselective conjugate reduction.
创建时间：
2016-02-26
