Synthesis and Structural Characterization of a Terminal Hydroxide Containing Alumoxane via Hydrolysis of Aluminum Hydrides
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https://figshare.com/articles/dataset/Synthesis_and_Structural_Characterization_of_a_Terminal_Hydroxide_Containing_Alumoxane_via_Hydrolysis_of_Aluminum_Hydrides/3349081
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资源简介:
A novel terminal hydroxide containing dinuclear alumoxane LAl(OH)OAlL(OCHN-tBu) (3; L = HC(CMeNAr)2, Ar = 2,6-iPr2C6H3)
was prepared by treatment of aluminum dihydride LAlH2 (1) and
tert-butyl isocyanate in the presence of trace amounts of water
and alternatively from 1 and LAlH(OCHN-tBu) (2) with water.
Compound 2 was obtained from the reaction of 1 and tert-butyl
isocyanate.
创建时间:
2004-02-23



