Synthesis and Structural Characterization of a Terminal Hydroxide Containing Alumoxane via Hydrolysis of Aluminum Hydrides
收藏NIAID Data Ecosystem2026-03-06 收录
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A novel terminal hydroxide containing dinuclear alumoxane LAl(OH)OAlL(OCHN-tBu) (3; L = HC(CMeNAr)2, Ar = 2,6-iPr2C6H3) was prepared by treatment of aluminum dihydride LAlH2 (1) and tert-butyl isocyanate in the presence of trace amounts of water and alternatively from 1 and LAlH(OCHN-tBu) (2) with water. Compound 2 was obtained from the reaction of 1 and tert-butyl isocyanate.
创建时间：
2004-02-23
