Enantioselective 1,2-Difunctionalization of Dienes Enabled by Chiral Palladium Complex-Catalyzed Cascade Arylation/Allylic Alkylation Reaction
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https://figshare.com/articles/dataset/Enantioselective_1_2_Difunctionalization_of_Dienes_Enabled_by_Chiral_Palladium_Complex_Catalyzed_Cascade_Arylation_Allylic_Alkylation_Reaction/2117134
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资源简介:
A Pd-catalyzed
highly enantioselective three-component coupling
of 1,3-dienes with aryl iodines and sodium dialkyl malonates has been
successfully established by using a H8-BINOL-based phosphoramidite
ligand. This reaction proceeded via a Pd-catalyzed cascade arylation
and asymmetric allylic alkylation reaction, providing an efficient
strategy for the enantioselective 1,2-difunctionalization
of 1,3-dienes.
创建时间:
2016-02-12



