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Shape-Selective Fluorescent Sensing Ensemble Using a Tweezer-Type Metalloreceptor

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https://figshare.com/articles/dataset/Shape_Selective_Fluorescent_Sensing_Ensemble_Using_a_Tweezer_Type_Metalloreceptor/3223228
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A fluorescent sensing ensemble for pyridine-derived compounds is described. The receptor portion of the ensemble is prepared from a bisimidazole pyridine which coordinates copper to form a well-defined cavity. Small heteroaromatic guests such as adenine bind strongly in the cavity. The fluorescent response is provided by a dye which is coordinated to the receptor and quenched by the metal ion. The dye is released upon guest binding providing up to 25-fold fluorescence increases.
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2016-05-05
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