Tetranuclear Ruthenium(II) Complex with a Dinucleating Ligand Forming Multi-Mixed-Valence States
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https://figshare.com/articles/dataset/Tetranuclear_Ruthenium_II_Complex_with_a_Dinucleating_Ligand_Forming_Multi_Mixed_Valence_States/2225557
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资源简介：
A square-shaped tetranuclear ruthenium(II) complex, [RuII4Cl5(bpmpm)2]3+ [1; bpmpm = 4,6-bis[[N,N-bis(2′-pyridylmethyl)amino]methyl]pyrimidine], exhibited four reversible and stepwise one-electron-oxidation processes: chemical oxidation of 1 formed three different mixed-valence states, in one of which the charge is partially delocalized on the two Ru centers, to be evidenced by observation of an intervalence charge-transfer absorption band, categorized into the Robin–Day class II.
创建时间：
2016-02-16
