Copper Ion Mediated Selective Cleavage of C–S Bond in Ferrocenylthiosemicarbazone Forming Mixed Geometrical [(PPh3)Cu(μ-S)2Cu(PPh3)2] Having Cu2S2 Core: Toward a New Avenue in Copper–Sulfur Chemistry
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https://figshare.com/articles/dataset/Copper_Ion_Mediated_Selective_Cleavage_of_C_S_Bond_in_Ferrocenylthiosemicarbazone_Forming_Mixed_Geometrical_PPh_sub_3_sub_Cu_S_sub_2_sub_Cu_PPh_sub_3_sub_sub_2_sub_Having_Cu_sub_2_sub_S_sub_2_sub_Core_Toward_a_New_Avenue_in_Copper_Sulfur_Chemistry/2539003
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资源简介：
Unprecedented selective cleavage of the carbon–sulfur bond of the ferrocenylthiosemicarbazone moiety has been observed for the first time, resulting in the formation of mixed geometrical binuclear copper complex [(PPh3)Cu(μ-S)2Cu(PPh3)2]. Upon trying direct synthesis of the title complex, an unusual tetranuclear [Cu4(μ3-Cl)4(PPh3)4] cubane resulted.
创建时间：
2016-02-21
