Fe-Catalyzed Allylic C–C-Bond Activation: Vinylcyclopropanes As Versatile a1,a3,d5-Synthons in Traceless Allylic Substitutions and [3 + 2]-Cycloadditions
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https://figshare.com/articles/dataset/Fe_Catalyzed_Allylic_C_C_Bond_Activation_Vinylcyclopropanes_As_Versatile_a1_a3_d5_Synthons_in_Traceless_Allylic_Substitutions_and_3_2_Cycloadditions/2538250
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资源简介：
The low-valent iron complex Bu4N[Fe(CO)3(NO)]
(TBAFe) catalyzes the allylic C–C-bond activation
of electron-poor vinyl cyclopropanes to generate synthetically useful
a1,a3,d5-synthons which are prone to undergo multiple consecutive
reactions. The versatility of this approach is demonstrated by a traceless
allylic substitution and a formal [3 + 2] cycloaddition to give either
functionalized acyclic products or densely substituted cyclopentanes
and pyrrolidines in high yields and regioselectivities.
创建时间：
2012-03-21
