Polymorphic Alternating HNN−Cobalt(II) Chains Both Behaving as Single-Chain Magnets (HNN = 4,4,5,5-Tetramethylimidazolin-1-oxyl 3-Oxide)
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https://figshare.com/articles/dataset/Polymorphic_Alternating_HNN_Cobalt_II_Chains_Both_Behaving_as_Single_Chain_Magnets_HNN_4_4_5_5_Tetramethylimidazolin_1_oxyl_3_Oxide_/3222388
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资源简介：
Metal-radical alternating chains [Co(hfac)2HNN]n crystallized in two
morphs containing repeating all-cis (α) and cis,cis,trans (β)
configurations with respect to the OHNN−Co−OHNN geometry (HNN
= 4,4,5,5-tetramethylimidazolin-1-oxyl 3-oxide). Both phases
showed magnetization jumps with hysteresis at 2 K. The α phase
has a relatively high activation energy of magnetization reorientation
(193 K).
创建时间：
2006-05-15
