Azopeptides: Synthesis and Pericyclic Chemistry
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https://figshare.com/articles/dataset/Azopeptides_Synthesis_and_Pericyclic_Chemistry/2112439
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资源简介：
Azopeptides possess an imino urea
as an amino amide surrogate in
the sequence. Azopeptides were synthesized by oxidation of aza-glycine
residues and employed in pericyclic chemistry. Diels–Alder
cyclizations and Alder–ene reactions on azopeptides enabled
construction of constrained aza-pipecolyl and reactive aza-allylglycyl
residues. X-ray crystallographic analyses of azopeptide 16a and azapeptides 30a and 35a provided insight
into imino urea configuration and conformational affects of cycloalkane
side chains at the semicarbazide α- and β-nitrogen, respectively.
创建时间：
2016-02-12
