Outer-Sphere Direction in Iridium C–H Borylation
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https://figshare.com/articles/dataset/Outer_Sphere_Direction_in_Iridium_C_H_Borylation/2504251
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The NHBoc group affords ortho selective C–H borylations in arenes and alkenes. Experimental and computational studies support an outer sphere mechanism where the N–H proton hydrogen bonds to a boryl ligand oxygen. The regioselectivities are unique and complement those of directed ortho metalations.
创建时间：
2016-02-20
