Tin Clathrates with the Type II Structure
收藏Figshare2016-02-19 更新2026-04-29 收录
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资源简介：
For a very long time, Ba16Ga32Sn104 has been the sole representative of tin clathrates with the type II structure. Herein, we present several new members of this structural family: Cs8Ba16Ga39.7(3)Sn96.3(3), Rb9.9(5)Ba13.3(2)Ga36.4(3)Sn99.6(3), and K2.0(4)Ba14.0(4)Ga30.4(2)Sn105.6(4). The successful synthesis of these novel compounds was facilitated through the use of alkali and alkaline-earth metals, which selectively fill the available cages.
创建时间：
2016-02-19
