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Rh2(II)-Catalyzed Selective Aminomethylene Migration from Styryl Azides

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Figshare2016-02-19 更新2026-04-29 收录
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https://figshare.com/articles/dataset/Rh_sub_2_sub_II_Catalyzed_Selective_Aminomethylene_Migration_from_Styryl_Azides/2443153
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Rh2(II)-Carboxylate complexes were discovered to promote the selective migration of aminomethylenes in β,β-disubstituted styryl azides to form 2,3-disubstituted indoles. Mechanistic data are also presented that suggest that the migration occurs stepwise before diffusion of the iminium ion.
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2016-02-19
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